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Soap Math

Ingredient Substitution Guide

When and how to swap ingredients without breaking your formula

Before You Substitute

Ingredient substitutions fall into two types: functional equivalents (same ingredient class, similar properties) and functional swaps (different ingredient, same job). Functional equivalents are usually straightforward — two fatty alcohols, two similar carrier oils. Functional swaps require more care because the new ingredient may behave differently even if it serves the same broad purpose.

The safest approach to any substitution:

  1. Make a small test batch (100–200 g) with the substituted ingredient
  2. Check appearance, texture, and skin feel immediately after making
  3. Observe stability over 2–4 weeks at room temperature and in a warm environment (40°C / 104°F)
  4. Only scale up once stability is confirmed

At a Glance

  • Same ingredient class = usually safe to swap; test anyway
  • Emulsifiers are the riskiest substitution — match HLB and usage rate
  • Never assume preservative substitutions are equivalent without testing
  • Wax substitutions: harder wax needs less; softer wax needs more
  • Oil swaps are generally forgiving if fatty acid profiles are similar

Wax Substitutions

IngredientSubstitute(s)Rate AdjustmentNotes
BeeswaxCandelilla waxUse ~50% of beeswax amountCandelilla is harder; adjust down
BeeswaxCarnauba waxUse ~25–30% of beeswax amountMuch harder; small amounts go far
BeeswaxRice bran wax1:1 starting pointSimilar hardness; test texture
Carnauba waxCandelilla wax~2:1 (candelilla is softer)Adjust for desired hardness
Candelilla waxCarnauba wax~1:2 (carnauba is harder)Adjust for desired hardness

Hardness Is Not Linear

Wax hardness varies significantly. Going from beeswax to candelilla in a 1:1 ratio typically produces a product that is too hard and brittle. Always start with the adjusted rate in the table above, then tweak based on your melt point testing.

Carrier Oil Substitutions

IngredientSubstitute(s)Key DifferenceNotes
Rosehip oilSea buckthorn (diluted), marula oilSimilar linoleic/vitamin A profileRosehip is high linoleic; prone to oxidation
Jojoba oilSqualaneSqualane is lighter; not technically an oil (liquid wax vs hydrocarbon)Both non-greasy; jojoba forms stronger barrier film
Sweet almond oilApricot kernel oilVery similar fatty acid profileNearly identical substitution
Coconut oilPalm kernel oilVery similar lauric acid contentNot vegan-acceptable for some; similar in formula
Castor oilNo close substituteUnique ricinoleic acid and viscosityIn soap: reduces lather if removed; in lip balm: provides gloss
Avocado oilMacadamia oilSimilar oleic content; macadamia has palmitoleic acidMacadamia is lighter in feel

Pro Tip

When substituting oils in cold process soap, check the new oil's SAP value in SoapMath — different oils saponify at different rates and the lye amount must be recalculated. Never assume the same lye amount applies after an oil swap.

Emulsifier Substitutions

Emulsifiers are the most consequential substitution in an emulsion. The table below is a starting point — treat every emulsifier substitution as a reformulation, not a swap.

EmulsifierSubstitute ApproachKey Consideration
Polawax (INCI: Emulsifying Wax NF)BTMS-50 (changes to cationic), or HLB-matched blendPolawax is nonionic self-emulsifying; substitutes change charge and HLB
Olivem 1000Combine cetearyl glucoside + cetearyl alcohol (Eumulgin B2 approach)Olivem is a naturally derived O/W emulsifier; match HLB ~10–11
BTMS-50BTMS-25 (lower behentrimonium content)BTMS-25 needs higher usage rate; different conditioning level
LecithinHydroxylated lecithin (better O/W stability)Lecithin alone forms unstable emulsions; usually used as co-emulsifier

Thickener Substitutions

ThickenerSubstitute(s)Notes
Xanthan gumHydroxyethylcellulose (HEC)HEC causes less pilling; similar viscosity at similar rates
Xanthan gumCarbomer (Carbopol)Requires neutralization; much higher viscosity at lower use rate
CarbomerSodium polyacrylateDifferent texture — more fluid gel; similar require-neutralization behavior
HECHydroxypropyl celluloseSimilar behavior; slightly different feel
Cetearyl alcohol (lotion body)Increase oil phase weightFatty alcohol provides body differently from gum thickeners — not 1:1

The most important distinction in thickener substitutions is between fatty alcohol thickeners (cetearyl alcohol, cetyl alcohol, stearyl alcohol) and polymer/gum thickeners (xanthan, carbomer, HEC). These are not interchangeable — fatty alcohols provide body through the oil phase and co-emulsifier effect; polymer thickeners provide viscosity through water-phase gelation. Substituting a polymer for a fatty alcohol (or vice versa) requires reconsidering the entire formula structure.

Vegan and Allergy-Related Substitutions

Common substitutions for allergen or ethical reasons:

  • Beeswax → Candelilla or carnauba wax (vegan): See wax table above. Adjust rate significantly.
  • Lanolin → Jojoba, shea butter, or mango butter (vegan/lanolin allergy): Not identical — lanolin has a unique occlusive-emollient character. Use a combination of occlusive (beeswax alternative + shea) to approximate.
  • Nut oils (almond, macadamia, hazelnut) → Sunflower, safflower, fractionated coconut (nut allergy): Sunflower and safflower are lightweight, high-linoleic alternatives. Fractionated coconut oil (caprylic/capric triglycerides) is stable and neutral. Derived from coconut, so may not be suitable for all coconut-sensitive individuals.
  • Honey → Sodium PCA or glycerin (vegan): Honey's humectant function can be approximated with humectants; its other skin-feel properties are harder to replicate exactly.

Frequently Asked Questions